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36037 Sigma-Aldrich

2′-(Dimethylamino)-2-biphenylyl-palladium(II) chloride Dinorbornylphosphine complex

≥99.0% (C)

Synonym: Chloro-[2′-(dimethylamino)-2-biphenylyl]-(dinorbornylphosphine)-palladium, SK-CC01-A

  • CAS Number 359803-53-5

  • Empirical Formula (Hill Notation) C28H37ClNPPd

  • Molecular Weight 560.45

  •  MDL number MFCD03427335

  •  PubChem Substance ID 57649461

  •  NACRES NA.22

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Homogeneous Pd Catalysts, Other Palladacycle Coupling Catalysts, Palladium Catalysts More...
InChI Key   YMZCYRNVJBOOCT-SBADXZPPSA-M
Quality Level   100
assay   ≥99.0% (C)
mp   160-170 °C (dec.) (lit.)
reaction suitability   reaction type: Buchwald-Hartwig Cross Coupling Reaction
  reaction type: Heck Reaction
  reaction type: Hiyama Coupling
  reaction type: Negishi Coupling
  reaction type: Sonogashira Coupling
  reaction type: Stille Coupling
  reaction type: Suzuki-Miyaura Coupling
  reagent type: catalyst

Description

Packaging

1, 5 g in glass bottle

Bottomless glass bottle. Contents are inside inserted fused cone.

Other Notes

Highly reactive, air and moisture stable palladium catalyst for C-C and C-N coupling reactions, e.g. Suzuki coupling, Heck reaction etc

Legal Information

sold in collaboration with Solvias AG

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles

Articles

Nájera Catalysts

Oxime-derived palladacycles 3 and 4 (Figure 2) introduced by Professor Carmen Nájera and co-workers at the Universidad de Alicante (Alicante, Spain) are very efficient phosphine-free precatalysts for...
Aldrich ChemFiles 2007, 7.5, 6.
Keywords: Chemfiles, Coupling reactions, Metallations, Solvents

Palladacycle Coupling Catalysts

Palladacyclic catalysts developed by Bedford’s group are examples of a select group of catalysts capable of affecting a variety of coupling reactions using difficult to activate aryl chlorides at ver...
William Sommer
ChemFiles 2007, 7.10, 17.
Keywords: Aminations, Catalysis, Coupling reactions, Ligands, Solvents, Stille coupling, Suzuki coupling

Peer-Reviewed Papers
15

References

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