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362891 Sigma-Aldrich

Diethylphosphoramidous dichloride

97%

Synonym: (Diethylamido)dichlorophosphite, (Diethylamino)dichlorophosphine, (Diethylamino)phosphine dichloride, Dichloro(diethylamido)phosphine, Dichloro(diethylamino)phosphine, Dichlorophosphorous diethylamide

  • CAS Number 1069-08-5

  • Linear Formula (C2H5)2NPCl2

  • Molecular Weight 174.01

  •  MDL number MFCD00013614

  •  PubChem Substance ID 24862338

  •  NACRES NA.22

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphorus Precursors
InChI Key   BPEMCEULJQTJMI-UHFFFAOYSA-N
Quality Level   100
assay   97%
refractive index   n20/D 1.497 (lit.)
bp   179 °C (lit.)
density   1.196 g/mL at 25 °C (lit.)
functional group   phosphine
reaction suitability   reaction type: Buchwald-Hartwig Cross Coupling Reaction
  reaction type: Heck Reaction
  reaction type: Hiyama Coupling
  reaction type: Negishi Coupling
  reaction type: Sonogashira Coupling
  reaction type: Stille Coupling
  reaction type: Suzuki-Miyaura Coupling
  reagent type: ligand
storage temp.   2-8°C

Description

Application

Reagent for the preparation of diethylaminophosphine-metal complexes and the phosphitylation of alcohols.

Packaging

5 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS05  GHS05
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 3265 8 / PGII
WGK Germany 
3
Flash Point(F) 
181.4 °F
Flash Point(C) 
83 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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