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363499 Sigma-Aldrich

1-Phenyl-1-hexyne

99%

Synonym: 1-Hexynylbenzene

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Properties

Related Categories Alkynes, Building Blocks, Chemical Synthesis, Internal, Organic Building Blocks More...
InChI Key   VBRLZTLFLNZEPZ-UHFFFAOYSA-N
assay   99%
refractive index   n20/D 1.5349 (lit.)
bp   229-232 °C(lit.)
density   0.9 g/mL at 25 °C (lit.)

Description

General description

1-Phenyl-1-hexyne is an alkyne. Stereoselective hydrogenation of 1-phenyl-1-hexyne at 298K and atmospheric pressure of H2 over Pd catalysts supported on mesostructured silica is reported. Polymerization of 1-phenyl-1-hexyne by pentahalides of niobium and tanatalum has been reported. Electrolytically induced, base-catalyzed isomerization of 1-phenyl-1-hexyne to 1-phenyl-1, 2-hexadiene in dimethylformamide containing tetra-n-butylammonium perchlorate using glassy carbon rotating ring-disk electrode has been reported.

Packaging

10 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Flash Point(F) 
208.4 °F
Flash Point(C) 
98 °C

Documents

Certificate of Analysis

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Protocols & Articles

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Keywords: Building blocks, Coupling reactions, Cross couplings

Peer-Reviewed Papers
15

References

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