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365424 Aldrich

1-Bromo-2-nitrobenzene

98%

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Properties

Related Categories Building Blocks, Chemical Synthesis, Nitro Compounds, Nitrogen Compounds, Organic Building Blocks More...
InChI Key   ORPVVAKYSXQCJI-UHFFFAOYSA-N
assay   98%
bp   261 °C(lit.)
mp   40-42 °C(lit.)
storage temp.   2-8°C

Description

Packaging

25, 100 g in glass bottle

Application

1-Bromo-2-nitrobenzene may be used in the preparation of:
• 4-methoxy-2′-nitrodiphenyl ether
• 1-methoxy-3,5-bis-(2-nitro-phenoxy)benzene
• 5-hydroxy-3-methoxy-2′-nitrodiphenyl ether

General description

1-Bromo-2-nitrobenzene undergoes palladium[0]-mediated Ullmann cross-coupling reaction with a range of β-halo-enals, -enones or -esters to afford the corresponding β-aryl derivatives. Palladium[0]-mediated Ullmann cross-coupling reaction of 1-bromo-2-nitrobenzene with β-bromo-α,β-unsaturated aldehydes is reported.

Price and Availability


Laboratory Gloves
Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
UN 3459 6.1 / PGIII
WGK Germany 
3
RTECS 
CY9040450
Flash Point(F) 
233.6 °F
Flash Point(C) 
112 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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