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369330 Sigma-Aldrich

N-tert-Butyltrimethylsilylamine

98%

Synonym: N-(Trimethylsilyl)-tert-butylamine

  • CAS Number 5577-67-3

  • Linear Formula (CH3)3SiNHC(CH3)3

  • Molecular Weight 145.32

  •  Beilstein/REAXYS Number 1734528

  •  MDL number MFCD00054891

  •  PubChem Substance ID 24862959

  •  NACRES NA.22

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Properties

Related Categories Building Blocks, Chemical Synthesis, Nitrogen Compounds - Organic Building Blocks, Organic Building Blocks, Protected Amines More...
Quality Level   100
assay   98%
refractive index   n20/D 1.406 (lit.)
bp   118-119 °C (lit.)
density   0.762 g/mL at 25 °C (lit.)
SMILES string   CC(C)(C)N[Si](C)(C)C
InChI   1S/C7H19NSi/c1-7(2,3)8-9(4,5)6/h8H,1-6H3
InChI key   GVHIREZHTRULPT-UHFFFAOYSA-N

Description

General description

N-tert-Butyltrimethylsilylamine (Me3SiNH-t-Bu) reacts with [Cp*Rh(H2O)3](OTf)2 in acetone to yield a hydroxyl-capped half-cubane [Cp*3Rh3(μ-OH)3(μ3-OH)](OTf)3(t-BuNH3).

Application

N-tert-Butyltrimethylsilylamine may be used in the preparation of selenium and tellurium chalcogenides and the facile synthesis of N-alkylaminomethylphosphonates.

Packaging

25 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 2733PSN1 8(3) / PGIII
WGK Germany 
WGK 3
Flash Point(F) 
78.8 °F - closed cup
Flash Point(C) 
26 °C - closed cup
Protocols & Articles
Peer-Reviewed Papers
15

References

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