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369799 Sigma-Aldrich

(tert-Butoxycarbonylmethylene)triphenylphosphorane

98%

Synonym: tert-Butyl(triphenylphosphoranylidene)acetate

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Properties

Related Categories C-C Bond Formation, Chemical Synthesis, Horner-Wadsworth-Emmons Reagents, Olefination, Synthetic Reagents More...
Quality Level   100
assay   98%
reaction suitability   reaction type: C-C Bond Formation
mp   152-155 °C (lit.)
storage temp.   2-8°C
SMILES string   CC(C)(C)OC(=O)C=P(c1ccccc1)(c2ccccc2)c3ccccc3
InChI   1S/C24H25O2P/c1-24(2,3)26-23(25)19-27(20-13-7-4-8-14-20,21-15-9-5-10-16-21)22-17-11-6-12-18-22/h4-19H,1-3H3
InChI key   ZWZUFQPXYVYAFO-UHFFFAOYSA-N

Description

Application

Wittig reagent used in the synthesis of aldose reductase inhibitors, a podophyllotoxin derivative, and tautomycin.
Versatile Wittig reagent used in medicinal chemistry.

Packaging

5, 25 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
RIDADR 
UN3464 - class 6.1 - PG 3 - EHS - Organophosphorus compound, toxic, solid, n.o.s., HI: all (not BR)
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Certificate of Origin (COO)

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Protocols & Articles
Peer-Reviewed Papers
15

References

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