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371440 Sigma-Aldrich

(1-tert-Butylvinyloxy)trimethylsilane

98%

Synonym: (2,2-Dimethyl-1-methylenepropoxy)trimethylsilane, 3,3-Dimethyl-2-trimethylsiloxy-1-butene, Pinacolone enol trimethylsilyl ether

  • CAS Number 17510-46-2

  • Linear Formula (CH3)3CC(=CH2)OSi(CH3)3

  • Molecular Weight 172.34

  •  Beilstein Registry Number 2204704

  •  MDL number MFCD00075567

  •  PubChem Substance ID 24863107

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Properties

Related Categories Building Blocks, Chemical Synthesis, Enol Ethers, Organic Building Blocks, Oxygen Compounds More...
InChI Key   PEHJULPJEVIIFJ-UHFFFAOYSA-N
assay   98%
refractive index   n20/D 1.409(lit.)
bp   140-142 °C(lit.)
density   0.798 g/mL at 25 °C(lit.)

Description

Packaging

5 g in glass bottle

Application

(1-tert-Butylvinyloxy)trimethylsilane ((2,2-Dimethyl-1-methylenepropoxy)trimethylsilane) may be used in the synthesis of cis-3,3-dimethyl-1-(6-phenethyl-3,6-dihydro-2H-pyran-2-yl)butan-2-one.

(1-tert-Butylvinyloxy)trimethylsilane may be used in the preparation of 1-(4-bromophenyl)-4,4-dimethylpentan-3-one.

General description

(1-tert-Butylvinyloxy)trimethylsilane is a silyl enol. It belongs to organosilicone class of compounds. Enthalpy of vaporization of (1-tert-Butylvinyloxy)trimethylsilane at boiling point has been reported.

Safety & Documentation

Safety Information

Symbol 
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
UN 1993C 3 / PGIII
WGK Germany 
3
Flash Point(F) 
75.2 °F
Flash Point(C) 
24 °C

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Peer-Reviewed Papers
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References

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