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376353 Sigma-Aldrich

Z-Phosphonoglycine trimethyl ester

97%

Synonym: (±)-Methyl 2-benzyloxycarbonylamino-2-(dimethoxyphosphinyl) acetate, (±)-Trimethyl Z-phosphonoglycinate, (±)-Z-Phosphonoglycine trimethyl ester

  • CAS Number 88568-95-0

  • Linear Formula (CH3O)2P(O)CH(NHCO2CH2C6H5)CO2CH3

  • Molecular Weight 331.26

  •  Beilstein/REAXYS Number 5764460

  •  MDL number MFCD00043304

  •  PubChem Substance ID 24863436

  •  NACRES NA.22

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Properties

Related Categories Chemical Biology, Chemical Synthesis, Glycine Derivatives, Peptide Synthesis and Peptide Chemistry, Unnatural Amino Acids & Derivatives More...
assay   97%
application(s)   peptide synthesis: suitable
mp   77-80 °C (lit.)
SMILES string   COC(=O)C(NC(=O)OCc1ccccc1)P(=O)(OC)OC
InChI   1S/C13H18NO7P/c1-18-12(15)11(22(17,19-2)20-3)14-13(16)21-9-10-7-5-4-6-8-10/h4-8,11H,9H2,1-3H3,(H,14,16)
InChI key   GSYSFVSGPABNNL-UHFFFAOYSA-N

Description

Packaging

5 g in glass bottle

Application

Starting material for the synthesis of (Z)-dehydroamino acids by Wittig-Horner reaction with aldehydes; the dehydroamino acids can be stereoselectively reduced to amino acids.

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable
Protocols & Articles
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