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377384 Sigma-Aldrich

Tetraamminepalladium(II) nitrate solution

10 wt. % in H2O

Synonym: Tetraamminedinitratopalladium, Tetraamminepalladium dinitrate

  • CAS Number 13601-08-6

  • Linear Formula Pd(NH3)4(NO3)2

  • Molecular Weight 298.55

  •  MDL number MFCD00011591

  •  PubChem Substance ID 24863500

  •  NACRES NA.22

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Homogeneous Pd Catalysts, Palladium Catalysts
Quality Level   100
reaction suitability   reaction type: Buchwald-Hartwig Cross Coupling Reaction
  reaction type: Heck Reaction
  reaction type: Hiyama Coupling
  reaction type: Negishi Coupling
  reaction type: Sonogashira Coupling
  reaction type: Stille Coupling
  reaction type: Suzuki-Miyaura Coupling
  reagent type: catalyst
concentration   10 wt. % in H2O
refractive index   n20/D 1.348
density   1.04 g/mL at 25 °C
SMILES string   N.N.N.N.[Pd++].[O-][N+]([O-])=O.[O-][N+]([O-])=O
InChI   1S/2NO3.4H3N.Pd/c2*2-1(3)4;;;;;/h;;4*1H3;/q2*-1;;;;;+2
InChI key   WIDMMNCAAAYGKW-UHFFFAOYSA-N

Description

Packaging

5, 25 mL in glass bottle

Application

Precursor to heterogeneous platinum catalysts for isomerizing unfunctionalized alkanes.

Used to prepare a Pd/TS-1 catalyst for the in situ generation of H2O2 and subsequent oxidation of propylene to propylene oxide.

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
RIDADR 
UN 3139 5.1 / PGII
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Catalysts
Protocols & Articles
Peer-Reviewed Papers
15

References

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