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377538 Sigma-Aldrich

Heptyltriphenylphosphonium bromide

97%

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Properties

Related Categories C-C Bond Formation, Chemical Synthesis, Olefination, Synthetic Reagents, Wittig Reagents More...
assay   97%
mp   173-176 °C (lit.)
SMILES string   [Br-].CCCCCCC[P+](c1ccccc1)(c2ccccc2)c3ccccc3
InChI   1S/C25H30P.BrH/c1-2-3-4-5-15-22-26(23-16-9-6-10-17-23,24-18-11-7-12-19-24)25-20-13-8-14-21-25;/h6-14,16-21H,2-5,15,22H2,1H3;1H/q+1;/p-1
InChI key   WCZSOHSGMBVYFW-UHFFFAOYSA-M

Description

Application

Reactant for:
• Stereospecific rearrangement of epoxides to quaternary carbaldehydes
• Synthesis of the male pheromone of two species of termite Zootermopsis
• Regio- and stereoselective TEMPO oxidation
• Diastereoselective synthesis of climacostol for antitumor activity
• Enantioselective synthesis of chiral vinylphosphonate and phosphonate analogs of immunosuppressive agent FTY720
• Preparation of embelin derivatives with XIAP inhibitory and anticancer activity

Packaging

50 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis (COA)

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Protocols & Articles
Peer-Reviewed Papers
15

References

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