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378216 Sigma-Aldrich

1-Fluoro-2,4,6-trimethylpyridinium triflate

technical grade, 85%

Synonym: 1-Fluoro-sym-collidinium triflate

  • CAS Number 107264-00-6

  • Empirical Formula (Hill Notation) C9H11F4NO3S

  • Molecular Weight 289.25

  •  Beilstein/REAXYS Number 4777118

  •  MDL number MFCD00067525

  •  PubChem Substance ID 24863547

  •  NACRES NA.22

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Properties

Related Categories Chemical Synthesis, Fluorination, Fluorination Reagents, Synthetic Reagents
grade   technical grade
assay   85%
mp   162-165 °C (lit.)
SMILES string   [O-]S(=O)(=O)C(F)(F)F.Cc1cc(C)[n+](F)c(C)c1
InChI   1S/C8H11FN.CHF3O3S/c1-6-4-7(2)10(9)8(3)5-6;2-1(3,4)8(5,6)7/h4-5H,1-3H3;(H,5,6,7)/q+1;/p-1
InChI key   PRIGFEJKMMRJSF-UHFFFAOYSA-M

Description

Application

Reactant for:
• Pd(II)-catalyzed para-selective C-H arylation
• Fluorination reactions
• Oxidant in oxidatively-induced aryl-CF3 bond-formation
• Pd(II)-catalyzed C-H olefination reactions

Packaging

1 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS05  GHS05
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 3261 8 / PGII
WGK Germany 
3
Protocols & Articles
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