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381411 Sigma-Aldrich

Triirondodecacarbonyl

contains 1-10% methyl alcohol

Synonym: Dodecacarbonyltriiron, tri-Irondodecacarbonyl

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Iron, Iron Catalysts, Non-Precious Metal Catalysis More...
contains   1-10% methyl alcohol
mp   165 °C (dec.) (lit.)
reaction suitability   reagent type: catalyst
storage temp.   2-8°C
SMILES string   [C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].O=C1[Fe]23[Fe][Fe]12C3=O
InChI   1S/12CO.3Fe/c12*1-2;;;
InChI key   HLYRMDDXFDINCB-UHFFFAOYSA-N

Description

Application

Eliminates sulfur from substituted thiophene complexes, leading to ferroles. Access to new areas of organometallic chemistry is promising using the reaction of Fe3(CO)12 with tellurium-nitrogen heterocycles such as benzoisotellurazole.

Packaging

5, 25 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 3175 4.1 / PGII
WGK Germany 
3
Flash Point(F) 
48.2 °F
Flash Point(C) 
9 °C

Documents

Certificate of Analysis (COA)

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Protocols & Articles
Peer-Reviewed Papers
15

References

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