• USA Home
  • 388076 - tert-Butyl peracetate solution

EMAIL THIS PAGE TO A FRIEND
388076 Sigma-Aldrich

tert-Butyl peracetate solution

50 wt. % in odorless mineral spirits

Purchase

Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Free Radical Initiators, Materials Science, Organic Peroxides,
InChI Key   SWAXTRYEYUTSAP-UHFFFAOYSA-N
t1/2   10 hr(101 °C, 0.2 M in benzene)
concentration   50 wt. % in odorless mineral spirits
refractive index   n20/D 1.412
density   0.828 g/mL at 25 °C

Description

Application

Allows the direct copper catalyzed acetoxylation of β-lactams at the 4-position.

Reagent used as a methyl-radical source under photoredox catalysis in conjunction with photocatalyst [Ir{dF(CF3)ppy}2(dtbpy)]PF6 (Aldrich L511765) for late-stage functionalization of biologically active heterocycles.

Late-Stage Functionalization of Biologically Active Heterocycles Through Photoredox Catalysis

Packaging

500 mL in poly bottle

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
RIDADR 
UN 3103A7 5.2
WGK Germany 
3
Flash Point(F) 
98.6 °F
Flash Point(C) 
37 °C
Protocols & Articles

Articles

Photocatalysis

Visible light photoredox catalysis has emerged as a powerful tool in organic synthesis, building upon the foundation set by early pioneers in the areas of radical chemistry and photochemistry. Photor...
Keywords: Capillary electrophoresis, Catalysis, Cross couplings, Cycloadditions, Degradations, Drug discovery, Gas chromatography, Infrared spectroscopy, Organic synthesis, Oxidations, Reductions, Scintillation, transformation

Peer-Reviewed Papers
15

References

Related Products

Technical Service:

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Bulk Ordering & Pricing:

Need larger quantities for your development, manufacturing or research applications?