• USA Home
  • 388076 - tert-Butyl peracetate solution

EMAIL THIS PAGE TO A FRIEND
388076 Sigma-Aldrich

tert-Butyl peracetate solution

50 wt. % in odorless mineral spirits

Synonym: tert -Butyl peracetate, tert -Butyl peroxyacetate

  • CAS Number 107-71-1

  • Linear Formula CH3CO3C(CH3)3

  • Molecular Weight 132.16

  •  MDL number MFCD00048240

  •  PubChem Substance ID 24864203

  •  NACRES NA.23

Purchase

Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Free Radical Initiators, Materials Science, Organic Peroxides,
Quality Level   100
t1/2   10 hr(101 °C, 0.2 M in benzene)
concentration   50 wt. % in odorless mineral spirits
refractive index   n20/D 1.412
density   0.828 g/mL at 25 °C
SMILES string   CC(=O)OOC(C)(C)C
InChI   1S/C6H12O3/c1-5(7)8-9-6(2,3)4/h1-4H3
InChI key   SWAXTRYEYUTSAP-UHFFFAOYSA-N

Description

Application

Allows the direct copper catalyzed acetoxylation of β-lactams at the 4-position.

Reagent used as a methyl-radical source under photoredox catalysis in conjunction with photocatalyst [Ir{dF(CF3)ppy}2(dtbpy)]PF6 (Aldrich L511765) for late-stage functionalization of biologically active heterocycles.

Late-Stage Functionalization of Biologically Active Heterocycles Through Photoredox Catalysis

Packaging

500 mL in poly bottle

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Target organs 
Respiratory system
RIDADR 
UN 3103A7 5.2
WGK Germany 
WGK 3
Flash Point(F) 
98.6 °F - closed cup
Flash Point(C) 
37 °C - closed cup
Protocols & Articles

Articles

Photocatalysis

Visible light photoredox catalysis has emerged as a powerful tool in organic synthesis, building upon the foundation set by early pioneers in the areas of radical chemistry and photochemistry. Photor...
Keywords: Capillary electrophoresis, Catalysis, Cross couplings, Cycloadditions, Degradations, Drug discovery, Gas chromatography, Infrared spectroscopy, Organic synthesis, Oxidations, Reductions, Scintillation, transformation

Peer-Reviewed Papers
15

References

Related Products

Technical Service:

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Bulk Ordering & Pricing:

Need larger quantities for your development, manufacturing or research applications?