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390380 Sigma-Aldrich

4-Acetamido-TEMPO, free radical

97%

Synonym: 4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxyl

  • CAS Number 14691-89-5

  • Empirical Formula (Hill Notation) C11H21N2O2

  • Molecular Weight 213.30

  •  Beilstein/REAXYS Number 3546225

  •  EC Number 423-840-3

  •  MDL number MFCD00043593

  •  PubChem Substance ID 24864140

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Properties

Related Categories Chemical Synthesis, Radical Chemistry, Stable Radicals, Synthetic Reagents, TEMPO Derivatives More...
InChI Key   UXBLSWOMIHTQPH-UHFFFAOYSA-N
assay   97%
mp   143-145 °C (lit.)

Description

Application

Oxidizes alcohols to carbonyl compounds in the presence of TsOH.

Packaging

25 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
1

Documents

Certificate of Analysis

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Certificate of Origin

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Protocols & Articles

Articles

Stahl Group – Professor Product Portal

From our library of Articles, Sigma-Aldrich presents Stahl Group – Professor Product Portal
Keywords: Aerobic, Catalysis, Dehydrogenation, Filtration, Oxidations, Pharmaceutical, Purification

TEMPO Catalyzed Oxidations

TEMPO (2,2,6,6-Tetramethylpiperidinyloxy or 2,2,6,6-Tetramethylpiperidine 1-oxyl) and its derivatives are stable nitroxy radicals used as catalysts in organic oxidation reactions. TEMPO was discovere...
Keywords: Aerobic, Capillary electrophoresis, Catalysis, Chromatography, Coupling reactions, Oxidations, Polymerization reactions, Size-exclusion chromatography, Solvents

Peer-Reviewed Papers
15

References

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