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  • 392081 - Tris(2,4,6-trimethoxyphenyl)phosphine

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392081 Sigma-Aldrich

Tris(2,4,6-trimethoxyphenyl)phosphine

Synonym: TTMPP

  • CAS Number 91608-15-0

  • Linear Formula [(CH3O)3C6H2]3P

  • Molecular Weight 532.52

  •  MDL number MFCD00145467

  •  PubChem Substance ID 24864423

  •  NACRES NA.22

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphine Ligands
mp   155-160 °C (lit.)
functional group   phosphine
reaction suitability   reaction type: Buchwald-Hartwig Cross Coupling Reaction
  reaction type: Heck Reaction
  reaction type: Hiyama Coupling
  reaction type: Negishi Coupling
  reaction type: Sonogashira Coupling
  reaction type: Stille Coupling
  reaction type: Suzuki-Miyaura Coupling
  reagent type: ligand
SMILES string   COc1cc(OC)c(P(c2c(OC)cc(OC)cc2OC)c3c(OC)cc(OC)cc3OC)c(OC)c1
InChI   1S/C27H33O9P/c1-28-16-10-19(31-4)25(20(11-16)32-5)37(26-21(33-6)12-17(29-2)13-22(26)34-7)27-23(35-8)14-18(30-3)15-24(27)36-9/h10-15H,1-9H3
InChI key   JQKHNBQZGUKYPX-UHFFFAOYSA-N

Description

Application

Highly basic arylphosphine.

Packaging

5 g in glass bottle

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles
Peer-Reviewed Papers
15

References

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