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393436 Sigma-Aldrich

Tris(2,6-dimethoxyphenyl)phosphine

98%

Synonym: DMPP

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Properties

Related Categories Basic Phosphine Ligands, Catalysis and Inorganic Chemistry, Chemical Synthesis, Cross-Coupling, Phosphine Compounds,
InChI Key   CMLWFCUAXGSMBB-UHFFFAOYSA-N
assay   98%
mp   145-147 °C (lit.)

Description

Packaging

5 g in glass bottle

Application

Catalyst for:
• Preparation of chiral building blocks via hydroalkynylation reactions or ynolates
• Three-component aza-Morita-Baylis-Hillman reactions (aza-MBH)
• Atom-economic synthesis of nitrogen heterocycles and ynenoates from alkynes
• Oxycylizations of allendiols
• Enantioselective aldol reactions
• Pd-mediated cross-coupling, Pd- and Cu-mediated benzannulation reactions and copper-mediated dimerization reactions

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles
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