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394424 Sigma-Aldrich

(Allyloxycarbonylmethyl)triphenylphosphonium iodide

97%

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Properties

Related Categories C-C Bond Formation, Chemical Synthesis, Olefination, Synthetic Reagents, Wittig Reagents More...
assay   97%
mp   138 °C (dec.) (lit.)
SMILES string   [I-].C=CCOC(=O)C[P+](c1ccccc1)(c2ccccc2)c3ccccc3
InChI   1S/C23H22O2P.HI/c1-2-18-25-23(24)19-26(20-12-6-3-7-13-20,21-14-8-4-9-15-21)22-16-10-5-11-17-22;/h2-17H,1,18-19H2;1H/q+1;/p-1
InChI key   PJGRTFGJXKYEIH-UHFFFAOYSA-M

Description

Application

For the preparation of α,β-unsaturated esters from aldehydes and ketones. The allyl group can be conveniently removed by standard rhodium or palladium chemistry.

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
UN 2811 6.1 / PGII
WGK Germany 
3

Documents

Certificate of Analysis (COA)

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Protocols & Articles
Peer-Reviewed Papers
15

References

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