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395099 Sigma-Aldrich

Tris(4-fluorophenyl)phosphine

Green Alternative

98%

Synonym: Tri-(p-fluorophenyl)phosphine

  • CAS Number 18437-78-0

  • Linear Formula (FC6H4)3P

  • Molecular Weight 316.26

  •  Beilstein/REAXYS Number 919838

  •  MDL number MFCD00013553

  •  PubChem Substance ID 24864642

  •  NACRES NA.22

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Properties

Related Categories 12 Principles Aligned Products, Catalysis and Inorganic Chemistry, Chemical Synthesis, Greener Alternative Products, Greener Catalysts,
assay   98%
greener alternative product characteristics   Catalysis
Learn more about the Principles of Green Chemistry.
mp   79-83 °C (lit.)
functional group   phosphine
reaction suitability   reaction type: Buchwald-Hartwig Cross Coupling Reaction
  reaction type: Heck Reaction
  reaction type: Hiyama Coupling
  reaction type: Negishi Coupling
  reaction type: Sonogashira Coupling
  reaction type: Stille Coupling
  reaction type: Suzuki-Miyaura Coupling
  reagent type: ligand
SMILES string   Fc1ccc(cc1)P(c2ccc(F)cc2)c3ccc(F)cc3
InChI   1S/C18H12F3P/c19-13-1-7-16(8-2-13)22(17-9-3-14(20)4-10-17)18-11-5-15(21)6-12-18/h1-12H
InChI key   GEPJPYNDFSOARB-UHFFFAOYSA-N

Description

General description

Sigma Life Science is committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

Ligand for rhodium-catalyzed oxygenative addition to terminal alkynes for a greener synthesis esters, amides, and carboxylic acids.

Rhodium-Catalyzed Oxygenative Addition to Terminal Alkynes for the Synthesis of Esters, Amides, and Carboxylic Acids

Packaging

5 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles
Peer-Reviewed Papers
15

References

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