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401633 Sigma-Aldrich

1-Pyrenemethylamine hydrochloride

95%

Synonym: PMA

  • CAS Number 93324-65-3

  • Empirical Formula (Hill Notation) C17H13N · HCl

  • Molecular Weight 267.75

  •  MDL number MFCD00192425

  •  PubChem Substance ID 24865033

  •  NACRES NA.22

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Properties

Related Categories Amine Salts, Building Blocks, Chemical Synthesis, Nitrogen Compounds - Organic Building Blocks, Organic Building Blocks More...
Quality Level   200
assay   95%
mp   258 °C (dec.) (lit.)
SMILES string   Cl[H].NCc1ccc2ccc3cccc4ccc1c2c34
InChI   1S/C17H13N.ClH/c18-10-14-7-6-13-5-4-11-2-1-3-12-8-9-15(14)17(13)16(11)12;/h1-9H,10,18H2;1H
InChI key   RGNMXKKNDSHTFD-UHFFFAOYSA-N

Description

General description

1-Pyrenemethylamine hydrochloride is an organic building block.

Application

1-Pyrenemethylamine (PyNH2) has also been used for the synthesis of:
• Pyrenyl hyaluronan (Py-HA), a pyrenyl-based polymer that can be used for the development of pH-triggered drug carriers.
• An electrochemical electrode of reduced graphene oxide bound with pyrene functionalized folic acid derivative.

It can also be used for the synthesis of 4,6-dichloro-2-pyrenemethylamine-1,3,5-triazine, a precursor to synthesize a star shaped polymer 4,6-bis(9H-carbazol-2-yloxy)-2-(pyrenemethylamine)-1,3,5 triazine (TPC).

1-Pyrenemethylamine hydrochloride (PyNH2) has been used for the loading of human telomerase reverse transcriptase (hTERT) small interfering RNA (siRNA) to the functionalized graphene oxide (GO) for the tumor targeting delivery of siRNA.

1-Pyrenemethylamine hydrochloride has been used in the preparation of 1-pyrenemethylamine. It may be used for the noncovalent functionalization of SWNTs with cationic moieties which binds strongly to the negatively charged phosphate backbone of the DNA. It may be used in the preparation of the following Schiff-base ligand:
• pyren-1-ylmethyl-[2-(6-{2-[(pyren-1-ylmethylimino)-methyl]-phenoxymethyl}-pyridin-2-ylmethoxy)-benzylidene]-amine
• 2(pyren-1-ylmethyl-{2-[6-(2-{[(pyren-1-ylmethyl)-amino]-methyl}- phenoxymethyl)-pyridin-2-ylmethoxy])-benzyl}-amine

Packaging

1, 5 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Target organs 
Respiratory system
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3

Documents

Certificate of Analysis (COA)

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Meet Synthia - Retrosynthesis Sofware
Protocols & Articles
Peer-Reviewed Papers
15

References

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