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40241 Sigma-Aldrich

(S)-(−)-N,N-Dimethyl-1-ferrocenylethylamine

≥98.0% (T)

Synonym: (S)-(−)-[1-(Dimethylamino)ethyl]ferrocene

  • CAS Number 31886-57-4

  • Empirical Formula (Hill Notation) C14H19FeN

  • Molecular Weight 257.15

  •  MDL number MFCD00066272

  •  PubChem Substance ID 57649950

  •  NACRES NA.22

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Other Chiral Ligands
assay   ≥98.0% (T)
optical activity   [α]20/D −14±1°, c = 1.5% in ethanol
color   dark brown
bp   120-121 °C/0.7 mmHg (lit.)
density   1.222 g/mL at 20 °C (lit.)
SMILES string   [Fe].[CH]1[CH][CH][CH][CH]1.C[C@@H]([C]2[CH][CH][CH][CH]2)N(C)C
InChI   1S/C9H14N.C5H5.Fe/c1-8(10(2)3)9-6-4-5-7-9;1-2-4-5-3-1;/h4-8H,1-3H3;1-5H;/t8-;;/m0../s1
InChI key   ISOLNZQTVMCEOI-JZGIKJSDSA-N

Description

Application

(S)-(−)-N,N-Dimethyl-1-ferrocenylethylamine can be used:
• As a starting material in the synthesis of chiral diferrocenylphosphine-diamines applicable in catalysis.
• As a model chiral probe in the study of enantiodiscrimination ability of chiral ionic liquids using cyclic voltammetry.

Packaging

1 mL in glass bottle

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
closed cup
Flash Point(C) 
closed cup
Protocols & Articles
Peer-Reviewed Papers
15

References

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