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403237 Sigma-Aldrich

Dichlorobis(tricyclohexylphosphine)palladium(II)

95%

Synonym: PdCl2[P(cy)3]2

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Homogeneous Pd Catalysts, Palladium Catalysts
InChI Key   VUYVXCJTTQJVKJ-UHFFFAOYSA-L
assay   95%
mp   270 °C (dec.) (lit.)

Description

Application

Catalyst for C-C and C-N coupling reaction.

Application Guide for Palladium Catalyzed Cross-Coupling Reactions

Packaging

1, 5 g in glass bottle

General description

Dichlorobis(tricyclohexylphosphine)palladium(II) is widely employed as catalyst precursor in various carbon-carbon and carbon-heteroatom bond forming reactions.

Safety & Documentation
Protocols & Articles

Articles

Heck Reaction

The Heck reaction is the palladium catalyzed cross-coupling reaction between alkenes, and aryl or vinyl halides (or triflates) to afford substituted alkenes.1,2 It is a useful carbon–carbon bond form...
Keywords: Asymmetric synthesis, Cancer, Catalysis, Coupling reactions, Cross couplings, Heck Reaction, Herbicides, Ligands, Organic synthesis, Solvents

Transition-Metal Catalysts

A variety of transition-metal catalysts for the Suzuki coupling reaction are now available in our catalog. The majority of these catalysts are palladium- and nickelbased, typically utilizing phosphin...
ChemFiles Volume 1 Article 1
Keywords: Coupling reactions, Ligands, Suzuki coupling

Related Content

Application Guide for Palladium Catalyzed Cross-Coupling Reactions

Palladium catalyzed cross-coupling reactions have revolutionized the way in which molecules are constructed. From the fields of organic synthesis and medicinal chemistry, to materials science and pol...
Keywords: Catalysis, Coupling reactions, Cross couplings, Materials Science, Medicinal chemistry, Organic synthesis, Polymer science, transformation

Peer-Reviewed Papers
15

References

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