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403547 Aldrich

3,6-Di-2-pyridyl-1,2,4,5-tetrazine

96%

  • CAS Number 1671-87-0

  • Empirical Formula (Hill Notation) C12H8N6

  • Molecular Weight 236.23

  •  MDL number MFCD00121717

  •  PubChem Substance ID 24865200

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Properties

Related Categories Building Blocks, Chemical Synthesis, Heterocyclic Building Blocks, N-Containing, Other Heterocyclic Building Blocks More...
InChI Key   JFBIRMIEJBPDTQ-UHFFFAOYSA-N
assay   96%
mp   225 °C (dec.)(lit.)

Description

Packaging

1, 5 g in glass bottle

Application

3,6-Di-2-pyridyl-1,2,4,5-tetrazine may be used in the following studies:
• Preparation of mononuclear, cyclic tetranuclear, and 1-D helical-chain Cu(II) complexes, via metal-assisted hydrolysis.
• Synthesis of novel cyclic tetranuclear ZnII complex.
• Synthesis of substituted 3,6-di(2-pyridyl)pyridazines, via inverse electron demand Diels Alder reaction with alkenes or alkynes.

General description

3,6-Di-2-pyridyl-1,2,4,5-tetrazine (DPTZ) undergoes solvothermal reaction with CuSO4.6H2O and Cu(Ac)2.H2O to afford copper containing coordination polymers. It reacts with enamine derivative of morpholine and 5-,6-,7- and 8-membered cyclic ketones to afford pyridazine derivatives.

3,6-Di-2-pyridyl-1,2,4,5-tetrazine undergoes solid-state reaction with fullerene C60 by high-speed vibration milling technique. It acts as electron-deficient diene in the inverse electron demand Diels Alder reaction.

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3

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Protocols & Articles
Peer-Reviewed Papers
15

References

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