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406139 Sigma-Aldrich

Chlorodicyclohexylborane

98%

Synonym: Dicyclohexylboron chloride, Dicyclohexylboryl chloride, Dicyclohexylchloroborane

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Properties

Related Categories Boranes, Chemical Synthesis, Reduction, Synthetic Reagents
InChI Key   PBBOKJIYEZCTEH-UHFFFAOYSA-N
assay   98%
bp   100-101 °C/1 mmHg(lit.)
density   0.97 g/mL at 25 °C (lit.)

Description

Application

A convenient reagent for regio- and stereoselective enolboration of ketones and other carbonyl derivatives.

Reactant for:
• Aldol addition reactions
• Mukaiyama aldol addition
• Microwave assisted ring closing metathesis reactions
• C-alkylation of aromatic aldimines
• Reversible ketone-ketone aldol reactions
• Syn- and anti-stereoselective aldol reaction hexenone with aldehydes

Packaging

25 mL in Sure/Seal™

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 2845 4.2
WGK Germany 
3
Flash Point(F) 
10.4 °F
Flash Point(C) 
-12 °C

Documents

Certificate of Analysis

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Protocols & Articles
Peer-Reviewed Papers
15

References

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