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407240 Sigma-Aldrich

Copper(I) trifluoromethanesulfonate benzene complex

technical grade, 90%

Synonym: Copper(I) triflate benzene complex, Cuprous trifluoromethanesulfonate benzene complex, Trifluoromethanesulfonic acid copper(I) salt benzene complex

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Copper Catalysts More...
grade   technical grade
InChI Key   GNXZWVVAAMVOJY-UHFFFAOYSA-L
assay   90%
mp   160 °C (dec.) (lit.)

Description

Application

In combination with amino acid-based chiral phosphine ligands, catalyzes asymmetric conjugate additions of alkylzincs to acyclic α,β-unsaturated ketones, affording β-alkylcarbonyls in high yield and with excellent enantioselectivity. Catalyzes allylic oxidation of cyclic alkenes enantioselectively.

Packaging

1, 5 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 3175 4.1 / PGII
WGK Germany 
3
Flash Point(F) 
44.6 °F
Flash Point(C) 
7 °C

Documents

Certificate of Analysis

Certificate of Origin

Protocols & Articles
Peer-Reviewed Papers
15

References

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