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409340 Sigma-Aldrich

Samarium(II) iodide

anhydrous, powder, ≥99.9% trace metals basis

Synonym: Samarium diiodide

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Crystal Grade Inorganics, Essential Chemicals, Materials Science,
Quality Level   100
grade   anhydrous
assay   ≥99.9% trace metals basis
form   powder
SMILES string   I[Sm]I
InChI   1S/2HI.Sm/h2*1H;/q;;+2/p-2
InChI key   UAWABSHMGXMCRK-UHFFFAOYSA-L

Description

Packaging

1, 5 g in ampule

Application

Promotes the cyanofluorination of aldehydes providing cyanofluorhydrins in good to excellent yield at room temperature in THF/HMPA.

Safety & Documentation

Safety Information

Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Certificate of Origin (COO)

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Protocols & Articles

Articles

Leighton’s Chiral Allylation Reagents

The asymmetric allylation of carbonyl compounds remains one of the most important and fundamental addition reactions for the synthesis of optically active chiral building blocks homoallylic alcohols.
Keywords: Addition reactions, Asymmetric synthesis, Building blocks, Medicinal chemistry, Reductions

The Rare Earth Crisis—The Supply/Demand Situation for 2010–2015

K.A. Gschneidner, Jr. Ames Laboratory, U.S. Department of Energy and Department of Materials Science and Engineering Iowa State University, Ames, Iowa 50011-3020, USA Email: cagey@ameslab.gov
Keywords: Absorption, Automotive, Capillary electrophoresis, Catalysis, Ceramics, Coloring agents, Detection methods, Environmental, Industries, Magnetic resonance imaging, Materials Science, Oxidations, Poisons, Reductions, Scintillation, Semiconductor, Separation, Substitutions

Peer-Reviewed Papers
15

References

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