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412015 Sigma-Aldrich

3-Bromo-4-methoxybenzaldehyde

98%

Synonym: 3-Bromo-p-anisaldehyde

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Properties

Related Categories Aldehydes, Building Blocks, C8, Carbonyl Compounds, Chemical Synthesis,
InChI Key   QMPNFQLVIGPNEI-UHFFFAOYSA-N
assay   98%
mp   51-54 °C (lit.)

Description

General description

3-Bromo-4-methoxybenzaldehyde is formed by the solvent-free bromination of 4-methoxybenzaldehyde using 1,3-di-n-butylimidazolium tribromide, as a brominating reagent.

Application

3-Bromo-4-methoxybenzaldehyde may be used in the following studies:
• Asymmetric synthesis of a novel β-hydroxy-α-amino acid derivative, via Mukaiyama aldol reaction.
• Synthesis of 2-(3-bromo-4-methoxyphenyl)-5-fluorobenzothiazole.
• Preparation of 5-[(Z)-2-(3-bromo-4-methoxyphenyl)vinyl]-1,2-3-trimethoxybenzene.
• Total synthesis of engelhardione.
• Starting reagent for the synthesis of (2E)-3-(3-bromo-4-methoxyphenyl)-1-(4-methylphenyl)prop-2-en-1-one.

Packaging

5, 25 g in glass bottle

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis

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Protocols & Articles
Peer-Reviewed Papers
15

References

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