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416665 Sigma-Aldrich

tert-Butyl hydroperoxide solution

5.0-6.0 M in decane

Synonym: 1,1-Dimethylethyl hydroperoxide, 2-Hydroperoxy-2-methylpropane, TBHP

  • CAS Number 75-91-2

  • Linear Formula (CH3)3COOH

  • Molecular Weight 90.12

  •  Beilstein/REAXYS Number 1098280

  •  MDL number MFCD00002130

  •  PubChem Substance ID 24865918

  •  NACRES NA.23

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Properties

Related Categories Chemical Synthesis, Free Radical Initiators, Materials Science, Organic Peroxides, Oxidizing Agents,
concentration   5.0-6.0 M in decane
impurities   <4% water
refractive index   n20/D 1.402
density   0.808 g/mL at 25 °C
storage temp.   2-8°C
SMILES string   CC(C)(C)OO
InChI   1S/C4H10O2/c1-4(2,3)6-5/h5H,1-3H3
InChI key   CIHOLLKRGTVIJN-UHFFFAOYSA-N

Description

General description

tert-Butyl hydroperoxide is an organic peroxide, used in oxidation processes.

Application

tert-Butyl hydroperoxide may be used in:
osmium catalyzed vicinal hydroxylation of olefins under alkaline conditions
catalytic asymmetric oxidation of sulfides to sulfoxides using binaphthol as a chiral auxiliary
oxidation of dibenzothiophenes

Packaging

25, 100 mL in poly bottle

Safety & Documentation

Safety Information

Signal word 
Danger
RIDADR 
UN 3105A8 8(5.2)
WGK Germany 
WGK 3
Flash Point(F) 
109.4 °F - closed cup
Flash Point(C) 
43 °C - closed cup

Documents

Certificate of Analysis (COA)

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Certificate of Origin (COO)

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Protocols & Articles
Peer-Reviewed Papers
15

References

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