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417521 Sigma-Aldrich

3-Chlorophenylboronic acid

≥95%

Synonym: (m-Chlorophenyl)boronic acid, 3-Chlorobenzeneboronic acid, m-Chlorobenzeneboronic acid

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Properties

Related Categories Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Monosubstituted Aryl Boronic Acids,
InChI Key   SDEAGACSNFSZCU-UHFFFAOYSA-N
assay   ≥95%
mp   185-189 °C (lit.)

Description

Application

Reactant involved in:
• 1,4-conjugate addition reactions with ethenesulfonamides to form arylethanesulfonamides
• Suzuki-Miyaura reactions with dibromotrifluoromethylbenzene
• Cross-coupling reactions with diazoesters or potassium cyanate
• Synthesis of biarylketones and phthalides
• Synthesis of inhibitors including PDE4 inhibitors among others

Packaging

1, 10 g in glass bottle

Other Notes

Contains varying amounts of anhydride

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis

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Certificate of Origin

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Protocols & Articles

Articles

Arylboronic Acids

We are pleased to present its complete selection of arylboronic acids, the building blocks of the Suzuki coupling experiment. Most arylboronic acids readily undergo dehydration reactions to give a cy...
ChemFiles 2001, 1.1, 5.
Keywords: Building blocks, Coupling reactions, Dehydration reaction, Suzuki coupling

Boronic Acids - ChemFiles 2007

Most boronic acids readily undergo dehydration reactions to give a cyclic (trimer) anhydride. Our selection of boronic acids may contain varying amounts of this cyclic anhydride. Fortunately, the aci...
ChemFiles 2007, 7.7, 3.
Keywords: Coupling reactions, Dehydration reaction, Suzuki coupling

Peer-Reviewed Papers
15

References

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