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418293 Sigma-Aldrich

Sodium thiophenolate

technical grade, 90%

Synonym: Benzenethiol sodium salt, Sodium thiophenoxide, Thiophenol sodium salt

  • CAS Number 930-69-8

  • Linear Formula C6H5SNa

  • Molecular Weight 132.16

  •  Beilstein/REAXYS Number 3597302

  •  EC Number 213-224-0

  •  MDL number MFCD00066460

  •  PubChem Substance ID 24866217

  •  NACRES NA.22

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Properties

Related Categories Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfur Compounds, Thiol/Mercaptan Salts More...
grade   technical grade
assay   90%
mp   >300 °C (lit.)
SMILES string   [Na]Sc1ccccc1
InChI   1S/C6H6S.Na/c7-6-4-2-1-3-5-6;/h1-5,7H;/q;+1/p-1
InChI key   RZWQDAUIUBVCDD-UHFFFAOYSA-M

Description

General description

Sodium thiophenolate can be prepared from the reaction of sodium and thiophenol in diethyl ether.

Application

Sodium thiophenolate has been used for the synthesis of MCoTI-I and MCoTI-II cyclotides, which are naturally-occurring cyclic cystine-knot microprotein trypsin inhibitors. It may be employed in the following studies:
• As probe for the immunoassay and for the detection of label-free protein by surface-enhanced Raman scattering (SERS).
• Preparation of new cyclometalated 6-phenyl-4-(p-R-phenyl)-2,2′-bipyridyl (C--N--N)Pt(II) thiophenolate complexes.
• Synthesis of 1,3,5,7,9-pentakis(4-methoxyphenylthio)corannulene, 1,3,5,7,9-pentakis(2-naphthylthio)corannulene and 1,3,6,8-tetrakis(4-methoxyphenylthio)corannulene.
• Synthesis of Et4N+ salts of homoleptic arylthiolate Ti(IV) complex, [Ti(SPh)6]2-.

Packaging

10, 50 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS05  GHS05
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 1759 8 / PGIII
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Meet Synthia - Retrosynthesis Sofware
Protocols & Articles
Peer-Reviewed Papers
15

References

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