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420727 Sigma-Aldrich

Chloro(dimethylsulfide)gold(I)

Synonym: (Dimethylsulfide)gold(I) chloride

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Gold Catalysts, Gold Complexes
Quality Level   100
reaction suitability   core: gold
  reagent type: catalyst
SMILES string   Cl[Au].CSC
InChI   1S/C2H6S.Au.ClH/c1-3-2;;/h1-2H3;;1H/q;+1;/p-1
InChI key   YQALRAGCVWJXGB-UHFFFAOYSA-M

Description

Application

Chloro(dimethylsulfide)gold(I) can be used to synthesize a gold(I)-catalyst that can effectively catalyze intermolecular [2+2] cycloaddition of terminal alkynes with substituted alkenes to form substituted cyclobutenes under mild reaction conditions.
It can also be used to synthesize:
• chloro(trimesitylphosphine)gold(I)
• gold(I) N-heterocyclic carbene (NHC) complexes
• bis(carbene)gold(I) complex of ferrocenyl complexes
• gold(I) acetylide complexes

Packaging

1 g in glass bottle

250 mg in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Target organs 
Respiratory system
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles
Peer-Reviewed Papers
15

References

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