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423424 Aldrich

2-(Trimethylsiloxy)-1,3-cyclohexadiene

95%

  • CAS Number 54781-19-0

  • Empirical Formula (Hill Notation) C9H16OSi

  • Molecular Weight 168.31

  •  Beilstein Registry Number 2079140

  •  MDL number MFCD00274202

  •  PubChem Substance ID 24866492

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Properties

Related Categories Building Blocks, Chemical Synthesis, Enol Ethers, Organic Building Blocks, Oxygen Compounds More...
InChI Key   WPIRVUXAMPRMAY-UHFFFAOYSA-N
assay   95%
refractive index   n20/D 1.462(lit.)
bp   65 °C/7 mmHg(lit.)
density   0.899 g/mL at 25 °C(lit.)
storage temp.   2-8°C

Description

Packaging

5, 25 mL in glass bottle

Application

2-(Trimethylsiloxy)-1,3-cyclohexadiene may be used as a diene in the synthesis of isoquinuclidinone 2-aza[2.2.2]octa-3,5-dione by reacting with p-toluenesulfonyl cyanide.

General description

2-(Trimethylsiloxy)-1,3-cyclohexadiene ((cyclohexa-1,5-dien-1-yloxy)trimethylsilane) is silyl enol ether of cyclohexenone. The Diels–Alder reactions with dienophiles α-acetoxyacrylonitrile, acrylonitrile and α-chloroacrylonitrile has been studied.

Safety & Documentation

Safety Information

Symbol 
GHS02  GHS02
Signal word 
Warning
Hazard statements 
RIDADR 
UN 1993C 3 / PGIII
WGK Germany 
3
Flash Point(F) 
116.6 °F
Flash Point(C) 
47 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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