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423939 Aldrich

Phenyl trifluoromethanesulfonate

98%

Synonym: Phenyl triflate

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Properties

Related Categories Building Blocks, Chemical Synthesis, Organic Building Blocks, Organic Triflates, Sulfur Compounds More...
InChI Key   GRJHONXDTNBDTC-UHFFFAOYSA-N
assay   98%
refractive index   n20/D 1.435(lit.)
bp   99-100 °C/60 mmHg(lit.)
density   1.396 g/mL at 25 °C(lit.)

Description

Packaging

5 mL in glass bottle

Application

Phenyl trifluoromethanesulfonate (phenyl triflate) may be used in the following studies:
• As an arylating agent for the asymmetric α-arylation of ketones catalyzed by Pd(dba)2 and difluorphos.
• As a reactant in the one pot synthesis of carbazoles by palladium-catalyzed N-arylation of anilines with phenyl triflate followed by oxidative coupling.
• Synthesis of N-(2,6-diarylbenzoyl)anilines by diarylation of benzanilides with phenyl triflate in the presence of palladium-based catalyst.
• As an arylating agent in the synthesis of (R)-2-phenyl-2,3-dihydrofuran by the arylation of 2,3-dihydrofuran.

General description

Phenyl trifluoromethanesulfonate (phenyl triflate) is an aryl fluorosulphonate. It has been synthesized by the reaction of phenol with fluorosulphonic anhydride.

Price and Availability

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 2927 8(6.1) / PGII
WGK Germany 
3
Flash Point(F) 
159.8 °F
Flash Point(C) 
71 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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