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435465 Sigma-Aldrich

Poly(ethylene glycol)-block-poly(propylene glycol)-block-poly(ethylene glycol)

average Mn ~5,800

Synonym: PEG-PPG-PEG, Pluronic® P-123

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Properties

Related Categories Amphiphilic Block Copolymers, Biomaterials, Block Copolymers, Materials Science, Micro/NanoElectronics,
Quality Level   100
vapor density   >1 (vs air)
vapor pressure   <0.3 mmHg ( 20 °C)
feed ratio   20:70:20 (EO:PO:EO)
mol wt   average Mn ~5,800
composition   PEG, 30 wt. %
refractive index   n20/D 1.465
surface tension   34 dyn/cm, 25 °C, 0.1 wt. % in H2O
viscosity   350 cP(60 °C, Brookfield)(lit.)
transition temp   Tm (DSC) 39 °C (at peak)
  cloud point 90 °C (1 wt. % aqueous solution)
density   1.018 g/mL at 25 °C
HLB   7 - 9

Description

General description

PEG-PPG-PEG (Pluronic P123) symmetric triblock copolymer constitutes of poly(ethylene oxide)(PEO) and poly (propylene oxide) (PPO). The unique characteristic of PPO block exhibiting hydrophobicity at temperatures above 288K and solubility in water at temperatures below 288K lead to formation of micelle consisting of PEO-PPO-PEO triblock copolymers. Some studies report that the hydrophobic core contains PPO block and a hydrophilic corona is comprised of PEO block. In 30wt% aqueous solution Pluronic P123® forms a cubic gel phase.

Application

Hard and soft surface cleaners, defoamers in coatings and water treatment. Lubricant in metal working, anti-foaming aid and extender for linear and cross-linked polyesters and polyurethanes.

PEG-PPG-PEG is used in the preparation and coating of Fe-W-C(O) nanoparticles by sol gel technique. Also, employed as sacrificial templates to prepare ZnS nanospheres, nanoporous silica.

Packaging

1 L in poly bottle

250 mL in poly bottle

Features and Benefits

Surface active material whose properties are dependent on the hydrophilic (EO)/hydrophobic (PO) ratio. High EO content gives better o/w stabilizers.

Physical form

Terminal primary dihydroxy-functional oligomer.

Legal Information

Pluronic is a registered trademark of BASF

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
1
RTECS 
MD0911050

Documents

Certificate of Analysis (COA)

Please Enter a Lot Number

Certificate of Origin (COO)

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Frequently Asked Questions

Which document(s) contains shelf-life or expiration date information for a given product?
If available for a given product, the recommended re-test date or the expiration date can be found on the Certificate of Analysis.
How do I get lot-specific information or a Certificate of Analysis?
The lot specific COA document can be found by entering the lot number above under the "Documents" section.
How do I find price and availability?
There are several ways to find pricing and availability for our products.Once you log onto our website, you will find the price and availability displayed on the product detail page.You can contact any of our Customer Sales and Service offices to receive a quote. USA customers: 1-800-325-3010 orview local office numbers.
What is the Department of Transportation shipping information for this product?
Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.
What is the average molecular weight of Product No. 435465, Poly(ethylene glycol)-block-poly(propylene glycol)-block-poly(ethylene glycol)?
While we do not test the product to determine the molecular weight, our supplier reports the average molecular weight to be 5750.
What is the pour point of Product No. 435465, Poly(ethylene glycol)-block-poly(propylene glycol)-block-poly(ethylene glycol)?
Our supplier reports the pour point of product 435465 to be 31 °C.
I found an abbreviation of "HLB" on the webpage for Product No. 435465, Poly(ethylene glycol)-block-poly(propylene glycol)-block-poly(ethylene glycol)?
HLB is an empirical expression for the relationship of the hydrophilic ("water-loving") and hydrophobic ("water-hating") groups of a surfactant. The table below lists HLB values along with typical performance properties. The higher the HLB value, the more water-soluble the surfactant.
What is the water content of Product No. 435465, Poly(ethylene glycol)-block-poly(propylene glycol)-block-poly(ethylene glycol),?
While we do not test the product to determine the water content, our supplier reports the maximum water content allowed in Prouct No. 435465 is 0.4%.
What is the physical form of Product No. 435465, Poly(ethylene glycol)-block-poly(propylene glycol)-block-poly(ethylene glycol)supposed to be?
The specification sheet describes Product No. 435465 as a semi-solid. It looks like a paste.
My question is not addressed here, how can I contact Technical Service for assistance?
Ask a Scientist here.
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Protocols & Articles

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Synthesis of Mesoporous Materials

Mespoporous materials, also known as mesoporous molecular sieves, are a class of 3D-nanostructures with well-defined mesoscale (2–50 nm diameter) pores and surface areas up to 1000 m2/g.1 In terms of...
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Keywords: Absorption, Catalysis, Condensations, Diffusion, Sol-gel

Peer-Reviewed Papers
15

References

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