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441813 Sigma-Aldrich

5,10,15,20-Tetrakis(4-sulfonatophenyl)-21H,23H-porphine manganese(III) chloride

Dye content 70 %

  • CAS Number 90587-86-3

  • Empirical Formula (Hill Notation) C44H28ClMnN4O12S4

  • Molecular Weight 1023.36

  •  MDL number MFCD00216662

  •  PubChem Substance ID 24867706

  •  NACRES NA.23

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Properties

Related Categories Materials Science, Organic and Printed Electronics, Photonic and Optical Materials, Phthalocyanine and Porphyrin Dyes, Porphyrines More...
Quality Level   100
composition   Dye content, 70%
mp   >300 °C (lit.)
λmax   466 nm
SMILES string   OS(=O)(=O)c1ccc(cc1)-c2c3ccc(n3)c(-c4ccc(cc4)S(O)(=O)=O)c5ccc6c(-c7ccc(cc7)S(O)(=O)=O)c8ccc(n8)c(-c9ccc(cc9)S(O)(=O)=O)c%10ccc2n%10[Mn](Cl)n56
InChI   1S/C44H28N4O12S4.ClH.Mn/c49-61(50,51)29-9-1-25(2-10-29)41-33-17-19-35(45-33)42(26-3-11-30(12-4-26)62(52,53)54)37-21-23-39(47-37)44(28-7-15-32(16-8-28)64(58,59)60)40-24-22-38(48-40)43(36-20-18-34(41)46-36)27-5-13-31(14-6-27)63(55,56)57;;/h1-24H,(H,49,50,51)(H,52,53,54)(H,55,56,57)(H,58,59,60);1H;/q-2;;+3/p-1/b41-33-,41-34-,42-35-,42-37-,43-36-,43-38-,44-39-,44-40-;;
InChI key   WMITXTXHDITCGT-YKKPBKTHSA-M

Description

General description

5,10,15,20-Tetrakis(4-sulfonatophenyl)-21H,23H-porphine manganese(III) chloride is a metal–porphyrin. During luminol chemiluminescence reactions, it can act as a highly sensitive catalyst. On-line chemiluminescence detection with capillary electrophoresis of the product was investigated and the detection limit was determined to be 361 amol and 8.1 × 10–9 mol L–1.

Packaging

100 mg in glass insert

Safety & Documentation

Safety Information

Symbol 
GHS05  GHS05
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 2585PSN2 8 / PGIII
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles
Peer-Reviewed Papers
15

References

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