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451738 Sigma-Aldrich

Titanium(II) chloride

anhydrous, powder, 99.98% trace metals basis

Synonym: Dichlorotitanium, Titanium dichloride

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Properties

Related Categories ATRP, ATRP Metal Salts, Crystal Grade Inorganics, Essential Chemicals, Materials Science,
Quality Level   100
grade   anhydrous
assay   99.98% trace metals basis
form   powder
SMILES string   Cl[Ti]Cl
InChI   1S/2ClH.Ti/h2*1H;/q;;+2/p-2
InChI key   ZWYDDDAMNQQZHD-UHFFFAOYSA-L

Description

Packaging

1, 5 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Supplemental Hazard Statements 
EUH014
RIDADR 
UN 3200 4.2
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles

Articles

A Review of Mesoporous TiO2 Thin Films

Jinshu Wang*, Junshu Wu, Hongyi Li The Key Lab of Advanced Functional Materials, Ministry of Education China, School of Materials Science and Engineering, Beijing University of Technology, Beijing 10...
Keywords: Adsorption, Building blocks, Catalysis, Ceramics, Condensations, Cosmetics, Degradations, Diffraction, Eliminations, Evaporation, Materials Science, Oxidations, Polymerization reactions, Semiconductor, Separation, Sol-gel

A micro review of reversible addition/fragmentation chain transfer (RAFT) polymerization

Reversible addition/fragmentation chain transfer (RAFT) polymerization is a reversible deactivation radical polymerization (RDRP) and one of the more versatile methods for providing living characteri...
Keywords: Biomaterials, Living polymerization, Nanotechnology, Polymerization reactions, Radical polymerization, Reversible addition-fragmentation chain transfer polymerizations, transformation

Applying ARGET ATRP to the Growth of Polymer Brush Thin Films by Surface-initiated Polymerization

In 2006, Matyjaszewski and co-workers first described controlled radical polymerization by Activators ReGenerated by Electron Transfer Atom Transfer Radical Polymerization (ARGET ATRP),1-3 a developm...
Keywords: Antimicrobials, Ligands, Nanotubes, Oxidations, Polymerization reactions, Radical polymerization, Reductions, Reversible addition-fragmentation chain transfer polymerizations, Solution polymerization, Solvents

Concepts and Tools for RAFT Polymerization

Reversible addition/fragmentation chain transfer (RAFT) is a form of living radical polymerization. RAFT polymerization was discovered at CSIRO in 1998.1 It soon became the focus of intensive researc...
Keywords: Polymerization reactions, Radical polymerization, Reversible addition-fragmentation chain transfer polymerizations

Copper(I)-mediated Living Radical Polymerization in the Presence of Pyridylmethanimine Ligands

Emergence of living radical polymerization mediated by transition metal catalysts in 1995 was a seminal piece of work in the field of synthetic polymer chemistry.1-3 Since this date, many transition ...
Keywords: Catalysis, Condensations, Evaporation, Filtration, Ligands, Oxidations, Polymer science, Polymerization reactions, Precipitation, Purification, Radical polymerization, Reductions, Solvents

Mesoporous Titanium Dioxide Thin Films

Titanium dioxide (TiO2) is an important n-type semiconducting material that shows interesting characteristics such as photoswitchable surface wettability, high photocatalytic activity, bistable elect...
Jinshu Wang, Junshu Wu, Hongyi Li
Material Matters, Volume 7, Number 2, 2–6
Keywords: Adsorption, Building blocks, Catalysis, Ceramics, Condensations, Cosmetics, Degradations, Diffraction, Eliminations, Evaporation, Materials Science, Oxidations, Polymerization reactions, Semiconductor, Separation, Sol-gel

Nanostructured Materials Through Ultrasonic Spray Pyrolysis | Technical Article

Jin Ho Bang,1,2 Yuri T. Didenko,3 Richard J. Helmich,1,4 and Kenneth S. Suslick1* 1School of Chemical Sciences, University of Illinois at Urbana-Champaign, 600 S. Mathews Av., Urbana, IL 61801 USA 2C...
Keywords: Antimicrobials, Cancer, Catalysis, Characterizations, Chemical reactions, Condensations, Deposition, Diffusion, Electronics, Evaporation, Flow cytometry, Nanomaterials, Oxidations, Photovoltaics, Precipitation, Purification, Reductions, Semiconductor, Separation, Solar cells, Solvents, Thin film deposition

Nanostructured Materials Through Ultrasonic Spray Pyrolysis

Advances in materials have often been led by the development of new synthetic methods that provide control over size, morphology and structure. The preparation of materials in a scalable and continuo...
Jin Ho Bang, Yuri T. Didenko, Richard J. Helmich, and Kenneth S. Suslick
Material Matters, Volume 7, Number 2, 15–20
Keywords: Antimicrobials, Cancer, Catalysis, Characterizations, Chemical reactions, Condensations, Deposition, Diffusion, Electronics, Evaporation, Flow cytometry, Nanomaterials, Oxidations, Photovoltaics, Precipitation, Purification, Reductions, Semiconductor, Separation, Solar cells, Solvents, Thin film deposition

Thermoelectric Performance of Perovskite-type Oxide Materials - Material Matters, 2011, Volume 6, Number 4, 92–99

Lassi Karvonen, Petr Tomeš, Anke Weidenkaff* Laboratory for Solid State Chemistry and Catalysis Department of Mobility, Energy and Environment EMPA-Swiss Federal Laboratories for Materials Science an...
Lassi Karvonen, Petr Tomeš, Anke Weidenkaff
Material Matters, 2011, Volume 6, Number 4, 92–99
Keywords: Catalysis, Combustion, Degradations, Materials Science, Oxidations, Semiconductor, Substitutions

Thermoelectric Performance of Perovskite-type Oxide Materials - Materials Science

Lassi Karvonen, Petr Tomeš, Anke Weidenkaff* Laboratory for Solid State Chemistry and Catalysis Department of Mobility, Energy and Environment EMPA-Swiss Federal Laboratories for Materials Science an...
Keywords: Catalysis, Combustion, Degradations, Materials Science, Oxidations, Semiconductor, Substitutions

Tools for Performing ATRP (Atom Transfer Radical Polymerization)

Controlled radical polymerization (CRP) techniques have been reviewed in a number of articles1,2 and books,3 and include nitroxide-mediated polymerization (NMP),4-7 reversible addition fragmentation ...
Sebastian Grajales
Keywords: Ligands, Polymerization reactions, Purification, Radical polymerization, Reversible addition-fragmentation chain transfer polymerizations, Solution polymerization

Typical Procedures for Polymerizing via ATRP

The following two procedures describe two ATRP polymerization reactions as performed by Prof. Dave Hadddleton′s research group at the University of Warwick.
Keywords: Gas chromatography, Ligands, Nuclear magnetic resonance spectroscopy, Polymerization reactions, Size-exclusion chromatography, Solvents

Typical Procedures for Polymerizing via RAFT

RAFT (Reversible Addition/Fragmentation Chain Transfer) is a form of living radical polymerization involving conventional free radical polymerization of a substituted monomer in the presence of a sui...
Keywords: Nuclear magnetic resonance spectroscopy, Polymerization reactions, Radical polymerization, Reversible addition-fragmentation chain transfer polymerizations

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