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454427 Sigma-Aldrich

Methyldiphenylphosphine oxide

98%

Synonym: Diphenylmethylphosphine oxide, Methyldiphenyloxophosphine, NSC 407134

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphine Ligands
assay   98%
mp   111-115 °C (lit.)
functional group   phosphine
reaction suitability   reaction type: Buchwald-Hartwig Cross Coupling Reaction
  reaction type: Heck Reaction
  reaction type: Hiyama Coupling
  reaction type: Negishi Coupling
  reaction type: Sonogashira Coupling
  reaction type: Stille Coupling
  reaction type: Suzuki-Miyaura Coupling
  reagent type: ligand
SMILES string   CP(=O)(c1ccccc1)c2ccccc2
InChI   1S/C13H13OP/c1-15(14,12-8-4-2-5-9-12)13-10-6-3-7-11-13/h2-11H,1H3
InChI key   PEGCITODQASXKH-UHFFFAOYSA-N

Description

Application

Catalyst for:
• Chlorination and bromination (halogenation) of alcohols under Appel conditions
• Hydrosilylation reactions
• Enantioselective cyanosilylation of ketones

Packaging

5, 25 g in glass bottle

Other Notes

Tandem Mass Spectrometry data independently generated by Scripps Center for Metabolomics is available to view or download in PDF. 454427.pdf Tested metabolites are featured on Scripps Center for Metabolomics METLIN Metabolite Database. To learn more, visit sigma.com/metlin.

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
RTECS 
SZ0199480

Documents

Certificate of Analysis (COA)

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Certificate of Origin (COO)

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Protocols & Articles
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