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458139 Sigma-Aldrich

Luperox® TBH70X, tert-Butyl hydroperoxide solution

70 wt. % in H2O

Synonym: 1,1-Dimethylethyl hydroperoxide, 2-Hydroperoxy-2-methylpropane, tert-Butyl hydroperoxide solution, TBHP

  • CAS Number 75-91-2

  • Linear Formula (CH3)3COOH

  • Molecular Weight 90.12

  •  Beilstein/REAXYS Number 1098280

  •  MDL number MFCD00002130

  •  PubChem Substance ID 24869433

  •  NACRES NA.23

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Properties

Related Categories Chemical Synthesis, Free Radical Initiators, Materials Science, Organic Peroxides, Oxidizing Agents,
Quality Level   200
concentration   70 wt. % in H2O
refractive index   n20/D 1.386
bp   96.2 °C
density   0.93 g/mL at 25 °C
storage temp.   2-8°C
SMILES string   CC(C)(C)OO
InChI   1S/C4H10O2/c1-4(2,3)6-5/h5H,1-3H3
InChI key   CIHOLLKRGTVIJN-UHFFFAOYSA-N

Description

Application

Iron-Catalyzed Efficient Synthesis of Amides from Aldehydes and Amine Hydrochloride Salts

Iron-Catalyzed Efficient Synthesis of Amides from Aldehydes and Amine Hydrochloride Salts

Versatile reagent for oxidations.

Packaging

1, 4 L in poly bottle

18 L in poly drum

25, 100 mL in poly bottle

Legal Information

Product of Arkema Inc.

Luperox is a registered trademark of Arkema Inc.

Safety & Documentation

Safety Information

Signal word 
Danger
RIDADR 
UN 3109A1 8(5.2) / PGII
WGK Germany 
WGK 3
Flash Point(F) 
107.6 °F - closed cup - Not applicable
Flash Point(C) 
42 °C - closed cup - Not applicable

Documents

Certificate of Analysis (COA)

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Certificate of Origin (COO)

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Protocols & Articles

Articles

CBHA Ligands

Yamamoto and his group developed a new type of ligands based on the C2-symmetric chiral bishydroxamic acid (CBHA). These bidentate ligands have pendant "arms" that can be substituted with a variety o...
Dr. Daniel Weibel
Chemfiles Volume 10 Article 1
Keywords: Asymmetric synthesis, Building blocks, Epoxidations, Jacobsen Epoxidation, Ligands, Oxidations, Sharpless Epoxidation

Protocols

Boxed reaction: Baran Trifluoromethylation Reaction

Please consult the Safety Data Sheet for information regarding hazards and safe handling practices.
Keywords: Chromatography, Column chromatography

Late Stage Difluoroethylation - Baran's DFES Reagent

From our library of Protocols, Sigma-Aldrich presents Late Stage Difluoroethylation - Baran's DFES Reagent
Keywords: Chromatography, Column chromatography, Thin layer chromatography

Late Stage Difluoromethylation - Baran's DFMS Reagent

From our library of Protocols, Sigma-Aldrich presents Late Stage Difluoromethylation - Baran's DFMS Reagent
Keywords: Chromatography, Nuclear magnetic resonance spectroscopy, Thin layer chromatography

Trifluoromethylation Kit

Please consult the Safety Data Sheet for information regarding hazards and safe handling practices.
Keywords: Chromatography, Column chromatography, Gas chromatography, High performance liquid chromatography, Thin layer chromatography

Related Content

Medical Materials

Medical Device manufacturers partner with us to source quality raw materials, obtain supply chain security, and to leverage a wide range of services to accelerate product development. 
Keywords: Environmental, Microbiology, Pyrogens

Peer-Reviewed Papers
15

References

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