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459496 Sigma-Aldrich

9-Borabicyclo[3.3.1]nonane solution

0.4 M in hexanes

Synonym: 9-BBN

  • CAS Number 280-64-8

  • Empirical Formula (Hill Notation) C8H15B

  • Molecular Weight 122.02

  •  Beilstein Registry Number 605509

  •  MDL number MFCD00074742

  •  PubChem Substance ID 24869563

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Properties

Related Categories Boranes, Chemical Synthesis, Reduction, Synthetic Reagents
InChI Key   FEJUGLKDZJDVFY-OCAPTIKFSA-N
concentration   0.4 M in hexanes
bp   68-70 °C
density   0.691 g/mL at 25 °C

Description

Packaging

1 L in Sure/Seal™

100 mL in Sure/Seal™

Application

Protecting group for alkenes†

Reactant for:
• Linear SPPS synthesis of ubiquitin derivatives
• Copper-catalyzed cross-coupling reactions of organoboron compounds with primary alkyl halides and pseudohalides
• Intramolecular insertion of alkenes into palladium-nitrogen bonds
• Preparation of (phosphonoacetyl)ornithine to study effect on arginine biosynthetic genes in yeast
• Hetero-Diels-Alder reaction for synthesis of spirocyclic alkaloids

Safety & Documentation

Safety Information

Signal word 
Danger
RIDADR 
UN 3399A 4.3(3) / PGI
WGK Germany 
3

Documents

Certificate of Analysis

Certificate of Origin

Protocols & Articles
Peer-Reviewed Papers
15

References

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