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459925 Sigma-Aldrich

Platinum(IV) oxide

Green Alternative

surface area ≥75 m2/g

Synonym: Adam’s catalyst, NSC 402624, Platinic oxide, Platinum dioxide

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Properties

Related Categories 12 Principles Aligned Products, Catalysis and Inorganic Chemistry, Chemical Synthesis, Greener Alternative Products, Greener Catalysts,
Quality Level   200
composition   Pt, 79-83%
reaction suitability   core: platinum
  reagent type: catalyst
greener alternative product characteristics   Designing Safer Chemicals
Catalysis
Learn more about the Principles of Green Chemistry.
impurities   iron, low
surface area   ≥75 m2/g
mp   450 °C (lit.)
SMILES string   O=[Pt]=O
InChI   1S/2O.Pt
InChI key   YKIOKAURTKXMSB-UHFFFAOYSA-N

Description

General description

Prepared by Adams′ nitrate fusion method.

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Catalyst for:
• Hydrohydrazination reactions
• Oxidation of sugars
• Low-temperature oxidation of carbon monoxide
• Oxygen reduction reaction
• Hydrogenation reactions
• Hydrogenolysis of the cyclopropyl group into an isopropyl group
• Hydroxycyclopropanation reactions

Catalyst for hydrogenation of various functional groups; used as dehydrogenation catalyst; used for selective oxidation of primary alcohols.

Packaging

1, 5 g in glass bottle

250 mg in glass bottle

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 1479 5.1 / PGII
WGK Germany 
WGK 2

Documents

Certificate of Analysis (COA)

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Certificate of Origin (COO)

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Protocols & Articles

Related Content

The 12 Principles of Green Chemistry

The aim of green chemistry is to reduce chemical related impact on human health and virtually eliminate contamination of the environment through dedicated, sustainable prevention programs. Green chem...
Keywords: Building blocks, Catalysis, Degradations, Derivatizations, Environmental, Green chemistry, Separation, Solvents

Peer-Reviewed Papers
15

References

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