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461075 Sigma-Aldrich

1-(Trimethylsilyl)-2-pyrrolidinone

96%

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Properties

Related Categories Building Blocks, C4 to C8, Chemical Synthesis, Heterocyclic Building Blocks, Pyrrolidines More...
assay   96%
refractive index   n20/D 1.46 (lit.)
bp   90 °C/20 mmHg (lit.)
density   0.983 g/mL at 25 °C (lit.)
SMILES string   C[Si](C)(C)N1CCCC1=O
InChI   1S/C7H15NOSi/c1-10(2,3)8-6-4-5-7(8)9/h4-6H2,1-3H3
InChI key   LUBVCBITQHEVCJ-UHFFFAOYSA-N

Description

General description

1-(Trimethylsilyl)-2-pyrrolidinone has been prepared by refluxing a mixture of 2-pyrrolidinone, triethylamine and trimethylchlorosilane in benzene. It undergoes sulfenylation with phenyl disulfide to form the corresponding bissulfide as the major product.

Application

1-(Trimethylsilyl)-2-pyrrolidinone may be used for the preparation of 1-(diphenylphosphonio)pyrrolidin-2-one and 1-(1-adamantylcarbonyl)-2-pyrrolidinone.

Packaging

10 mL in glass bottle

Safety & Documentation

Safety Information

Symbol 
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
UN 1993C 3 / PGIII
WGK Germany 
3
Flash Point(F) 
127.4 °F
Flash Point(C) 
53 °C

Documents

Certificate of Analysis (COA)

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Certificate of Origin (COO)

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Meet Synthia - Retrosynthesis Sofware
Protocols & Articles
Peer-Reviewed Papers
15

References

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