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464309 Sigma-Aldrich

Methoxyperfluorobutane

99%, mixture of n- and iso-butyl isomers

Synonym: HFE-7100, Methoxynonafluorobutane, Methoxyperfluorobutane, Nonafluorobutyl methyl ether, Nonafluoromethoxybutane

  • CAS Number 163702-07-6

  • Linear Formula CH3OCF2R, R = -CF2CF2CF3 or -CF(CF3)2

  • Molecular Weight 250.06

  •  Beilstein/REAXYS Number 8768491

  •  PubChem Substance ID 24870162

  •  NACRES NA.22

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Properties

Related Categories Building Blocks, C2 to C7, Chemical Synthesis, Ethers, F-Tagged,
Quality Level   100
assay   99%
refractive index   n20/D 1.3 (lit.)
bp   60 °C (lit.)
mp   −135 °C (lit.)
density   1.52 g/mL at 25 °C (lit.)
SMILES string   COC(F)(F)C(F)(F)C(F)(F)C(F)(F)F.COC(F)(F)C(F)(C(F)(F)F)C(F)(F)F
InChI   1S/2C5H3F9O/c1-15-5(13,14)3(8,9)2(6,7)4(10,11)12;1-15-5(13,14)2(6,3(7,8)9)4(10,11)12/h2*1H3
InChI key   OKIYQFLILPKULA-UHFFFAOYSA-N

Description

Application

Methoxyperfluorobutane can be used as a solvent:
• In the synthesis of various aryl fluoride derivatives via electrophilic fluorination of aryl and heteroaryl Grignard reagents.
• In grafting of fluorinated diblock copolymers onto silica particles.

Packaging

100, 500 mL in glass bottle

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Certificate of Origin (COO)

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Protocols & Articles
Peer-Reviewed Papers
15

References

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