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466964 Sigma-Aldrich

4′-Fluoro-2′-hydroxyacetophenone

98%

  • CAS Number 1481-27-2

  • Linear Formula FC6H3(OH)COCH3

  • Molecular Weight 154.14

  •  MDL number MFCD00143203

  •  PubChem Substance ID 24870373

  •  NACRES NA.22

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Description

General description

4′-Fluoro-2′-hydroxyacetophenone is a substituted acetophenone derivative. Biological Baeyer-Villiger oxidation of 4′-fluoro-2′-hydroxyacetophenone to 4-fluorocatechol by using whole cells of Pseudomonas fluorescens ACB has been reported. Its crystals belong to the monoclinic crystal system and space group P21/n.

Application

4′-Fluoro-2′-hydroxyacetophenone may be used in the preparation of series of 4′-fluoro-2′-hydroxychalcones, via aldol condensation with substituted aldehydes followed by cyclization with hydrazine hydrate.

Used recently in the preparation of medicinally active benzo[b]furans and thiophenes.

Packaging

5 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Flash Point(F) 
210.2 °F
Flash Point(C) 
99 °C

Documents

Certificate of Analysis (COA)

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Certificate of Origin (COO)

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Protocols & Articles
Peer-Reviewed Papers
15

References

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