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467278 Sigma-Aldrich

N-Methyl-o-toluidine

≥95%

Synonym: 2,N-Dimethylaniline, 2-Methyl-N-methylaniline, N,2-Dimethylbenzenamine, N,2-Dimethylaniline, N,o-Dimethylaniline, N-(2-Methylphenyl)methylamine, N-Methyl-2-methylaniline, N-Methyl-2-methylbenzenamine, N-Methyl-N-(o-tolyl)amine, N-Methyl-o-methylaniline, o,N-Dimethylaniline, Methyl(o-tolyl)amine, NSC 9395

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Properties

Related Categories Amines, Building Blocks, C8, Chemical Synthesis, Nitrogen Compounds - Organic Building Blocks,
assay   ≥95%
bp   177-204 °C/740 mmHg (lit.)
density   0.981 g/mL at 25 °C (lit.)
SMILES string   CNc1ccccc1C
InChI   1S/C8H11N/c1-7-5-3-4-6-8(7)9-2/h3-6,9H,1-2H3
InChI key   GUAWMXYQZKVRCW-UHFFFAOYSA-N

Description

General description

N-Methyl-o-toluidine can be synthesized by reacting o-toluidine and benzotriazole.

Application

N-Methyl-o-toluidine may be used in the preparation of 2-substituted N-methylindoles.

Reactant for:
• Palladium-catalyzed coupling reactions
• Palladium-catalyzed amination of bromoindazoles

Packaging

25 mL in glass bottle

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
RIDADR 
UN 2810 6.1 / PGIII
WGK Germany 
WGK 3
Flash Point(F) 
174.9 °F - closed cup
Flash Point(C) 
79.4 °C - closed cup

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Protocols & Articles
Peer-Reviewed Papers
15

References

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