EMAIL THIS PAGE TO A FRIEND
467448 Sigma-Aldrich

Triethylsilane

97%

Synonym: NSC 93579, Triethylhydrosilane, Triethylsilicon hydride

  • CAS Number 617-86-7

  • Linear Formula (C2H5)3SiH

  • Molecular Weight 116.28

  •  Beilstein/REAXYS Number 1098278

  •  EC Number 210-535-3

  •  MDL number MFCD00009018

  •  PubChem Substance ID 24870410

  •  NACRES NA.22

Purchase

Properties

Related Categories Chemical Synthesis, Reduction, Silanes, Synthetic Reagents
assay   97%
refractive index   n20/D 1.412 (lit.)
bp   107-108 °C (lit.)
density   0.728 g/mL at 25 °C (lit.)
SMILES string   CC[SiH](CC)CC
InChI   1S/C6H16Si/c1-4-7(5-2)6-3/h7H,4-6H2,1-3H3
InChI key   AQRLNPVMDITEJU-UHFFFAOYSA-N

Description

Application

Catalyst for:
• Synthesis of a spiro-oxindole blocker of Nav1.7 for the treatment of pain
• Redox initiated cationic polymerization
• Beckmann rearrangement of cyclododecanone oxime
• Regioselective reductive coupling of enones and allenes

Catalyst reactivation after catalyst polymerization of styrene

Studies involving the prediction of organosilicon flash points

Triethylsilane can be used as:
• A reducing agent in the regioselective reductive coupling of enones and allenes.
• A reagent in the redox initiated cationic polymerization.
• A reagent in catalytic transfer hydrogenation, reduction of alkyl halides and silylation of aromatic C-H bonds, etc.
• As a reagent for the generation of indium hydride (Cl2InH) applicable as a catalyst for the intramolecular cyclization of enynes.

Packaging

25, 100 mL in Sure/Seal™

Safety & Documentation

Safety Information

Symbol 
GHS02  GHS02
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 1993BF 3 / PGII
WGK Germany 
1
Flash Point(F) 
26.6 °F
Flash Point(C) 
-3 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

Related Products

Technical Service:

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Bulk Ordering & Pricing:

Need larger quantities for your development, manufacturing or research applications?