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468347 Sigma-Aldrich

(R)-(+)-2-Bromo-3-methylbutyric acid

96%

  • CAS Number 76792-22-8

  • Linear Formula (CH3)2CHCH(Br)CO2H

  • Molecular Weight 181.03

  •  MDL number MFCD00210113

  •  PubChem Substance ID 24870509

  •  NACRES NA.22

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Properties

Related Categories Asymmetric Synthesis, Carboxylic Acids, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks More...
assay   96%
optical activity   [α]22/D +21°, c = 37 in benzene
bp   90-100 °C/0.5 mmHg (lit.)
mp   35-40 °C (lit.)
SMILES string   CC(C)[C@@H](Br)C(O)=O
InChI   1S/C5H9BrO2/c1-3(2)4(6)5(7)8/h3-4H,1-2H3,(H,7,8)/t4-/m1/s1
InChI key   UEBARDWJXBGYEJ-SCSAIBSYSA-N

Description

Application

(R)-(+)-2-Bromo-3-methylbutyric acid can be used:
• As an anionic counterpart of morpholinium based chiral ionic liquids applicable in the Heck arylation reaction of 2,3-dihydrofuran.
• As a starting material in the synthesis of fructosyl peptide oxidase inhibitors.

Packaging

5 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 3261 8 / PGII
WGK Germany 
WGK 3
Flash Point(F) 
235.4 °F - closed cup
Flash Point(C) 
113 °C - closed cup
Protocols & Articles
Peer-Reviewed Papers
15

References

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