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469424 Sigma-Aldrich

Methyl (2R)-glycidate

optical purity ee: 94% (GLC), 97%

Synonym: Methyl (R)-oxiranecarboxylate

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Epoxides, Organic Building Blocks More...
InChI Key   YKNYRRVISWJDSR-GSVOUGTGSA-N
assay   97%
optical activity   [α]20/D +32°, c = 1 in chloroform
optical purity   ee: 94% (GLC)
refractive index   n20/D 1.42 (lit.)
density   1.166 g/mL at 25 °C (lit.)
shipped in   wet ice
storage temp.   2-8°C

Description

Packaging

5, 25 g in glass bottle

Legal Information

Manufactured under license by Sterling Pharma Solutions Limited, using Jacobsen HKR technology.

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
NA 1993 / PGIII
WGK Germany 
3
Flash Point(F) 
161.6 °F
Flash Point(C) 
72 °C

Documents

Certificate of Analysis

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Certificate of Origin

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Protocols & Articles

Articles

HKR Epoxides

One of the most effective and recent methods for obtaining several classes of chiral building blocks is Jacobsen’s hydrolytic kinetic resolution technique (HKR). The method provides general access to...
Aldrich ChemFiles 2005, 5.4, 17.
Keywords: Anti-inflammatory agents, Asymmetric synthesis, Building blocks, Chemfiles, Deprotonations, Ligands, Methods

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