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470430 Sigma-Aldrich

2-(Trimethylsilyl)phenyl trifluoromethanesulfonate

97%

  • CAS Number 88284-48-4

  • Linear Formula CF3SO3C6H4Si(CH3)3

  • Molecular Weight 298.35

  •  MDL number MFCD00799598

  •  PubChem Substance ID 24870661

  •  NACRES NA.22

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Properties

Related Categories Building Blocks, Chemical Synthesis, Organic Building Blocks, Organic Triflates, Sulfur Compounds More...
assay   97%
refractive index   n20/D 1.456 (lit.)
bp   70 °C/2 mmHg (lit.)
density   1.229 g/mL at 25 °C (lit.)
storage temp.   room temp
SMILES string   C[Si](C)(C)c1ccccc1OS(=O)(=O)C(F)(F)F
InChI   1S/C10H13F3O3SSi/c1-18(2,3)9-7-5-4-6-8(9)16-17(14,15)10(11,12)13/h4-7H,1-3H3
InChI key   XBHPFCIWRHJDCP-UHFFFAOYSA-N

Description

General description

2-(Trimethylsilyl)phenyl trifluoromethanesulfonate is an important ortho-benzyne precursor in aryne chemistry.

Application

2-(Trimethylsilyl)phenyl trifluoromethanesulfonate may be used to generate benzyne under mild conditions of simple fluoride treatment at room temperature.

Packaging

1, 5 g in glass bottle

Safety & Documentation

Safety Information

RIDADR 
UN 3265 8 / PGII
WGK Germany 
WGK 3

Documents

Certificate of Analysis (COA)

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Certificate of Origin (COO)

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Protocols & Articles
Peer-Reviewed Papers
15

References

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