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470805 Sigma-Aldrich

2-Acetylphenylboronic acid

≥95%

Synonym: 2-Acetylbenzeneboronic acid

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Properties

Related Categories Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Monosubstituted Aryl Boronic Acids,
Quality Level   100
assay   ≥95%
mp   170 °C (dec.) (lit.)
SMILES string   CC(=O)c1ccccc1B(O)O
InChI   1S/C8H9BO3/c1-6(10)7-4-2-3-5-8(7)9(11)12/h2-5,11-12H,1H3
InChI key   ZKAOVABYLXQUTI-UHFFFAOYSA-N

Description

Application

Reactant involved in:
• Suzuki-Miyaura cross-coupling reactions
• Rhodium-catalyzed annulation of ynamides
• Transient masking of hydroxy groups
• Cationic palladium complex-catalyzed diastereoselective tandem annulation
• Hydrogen peroxide mediated formation of heteroaryl ethers
• Copper-catalyzed transmetalation and homocoupling

Packaging

5, 25 g in glass bottle

Other Notes

Contains varying amounts of anhydride

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Target organs 
Respiratory system
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Protocols & Articles

Articles

Arylboronic Acids

We are pleased to present its complete selection of arylboronic acids, the building blocks of the Suzuki coupling experiment. Most arylboronic acids readily undergo dehydration reactions to give a cy...
ChemFiles 2001, 1.1, 5.
Keywords: Building blocks, Coupling reactions, Dehydration reaction, Suzuki coupling

Boronic Acids - ChemFiles 2007

Most boronic acids readily undergo dehydration reactions to give a cyclic (trimer) anhydride. Our selection of boronic acids may contain varying amounts of this cyclic anhydride. Fortunately, the aci...
ChemFiles 2007, 7.7, 3.
Keywords: Coupling reactions, Dehydration reaction, Suzuki coupling

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