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  • 474614 - Tetrakis[1-[(4-tert-butylphenyl)sulfonyl]-(2S)-pyrrolidinecarboxylate]dirhodium(II)

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474614 Sigma-Aldrich

Tetrakis[1-[(4-tert-butylphenyl)sulfonyl]-(2S)-pyrrolidinecarboxylate]dirhodium(II)

Synonym: Rh2(S-TBSP)4

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Properties

Related Categories Asymmetric Synthesis, Aziridination/Cyclopropanation, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents
optical activity   [α]20/D −187°, c = 0.1 in chloroform
mp   273 °C (dec.) (lit.)
SMILES string   CC(C)(C)c1ccc(cc1)S(=O)(=O)N2CCC[C@H]2C(=O)O[Rh]OC(=O)[C@@H]3CCCN3S(=O)(=O)c4ccc(cc4)C(C)(C)C.CC(C)(C)c5ccc(cc5)S(=O)(=O)N6CCC[C@H]6C(=O)O[Rh]OC(=O)[C@@H]7CCCN7S(=O)(=O)c8ccc(cc8)C(C)(C)C
InChI   1S/4C15H21NO4S.2Rh/c4*1-15(2,3)11-6-8-12(9-7-11)21(19,20)16-10-4-5-13(16)14(17)18;;/h4*6-9,13H,4-5,10H2,1-3H3,(H,17,18);;/q;;;;2*+2/p-4/t4*13-;;/m0000../s1
InChI key   HVKPLPQGLBYKLH-WYIKOJPOSA-J

Description

Application

Catalyst for asymmetric cyclopropanations.

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
WGK Germany 
3

Documents

Certificate of Analysis (COA)

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Protocols & Articles
Peer-Reviewed Papers
15

References

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