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477400 Sigma-Aldrich

(Acetonitrile)trichlorobis(triphenylphosphine)rhenium(III)

97%

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Rhenium Catalysts More...
Quality Level   100
assay   97%
reaction suitability   reagent type: catalyst
mp   210 °C (dec.) (lit.)
SMILES string   CC#N.Cl[Re](Cl)Cl.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6
InChI   1S/2C18H15P.C2H3N.3ClH.Re/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2-3;;;;/h2*1-15H;1H3;3*1H;/q;;;;;;+3/p-3
InChI key   SEHZOVVCPGBXNW-UHFFFAOYSA-K

Description

Application

Catalyst for addition of tetrahalomethanes to alkenes and 1-omega-dienes

Reactant for synthesis of:
• Re(III) complexes containing 2-benzoylpyridine
• Rhenium(IV) and (V) complexes
• Rhenium triphosphorus macrocycle complexes and reactions with alkenes

Reactant for rhenium chemistry of azooximes

Packaging

1 g in glass bottle

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Catalysts
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